Hydrogen is a clean energy source that is commonly available in the natural world.As an alternative energy option, hydrogen proves exceptionally valuable as green fuel.Hydrogen fuel cells further contribute to unprecedented vehicle efficiencies.One of the main obstacles to hydrogen′s widespread use as an energy source is its safe and effective storage.Because of their intrinsic characteristics, COF-MTF stands out as a new family exhibit notable flexibility and a porous structure making them versatile for hydrogen storage and clean energy applications.This study aimed to develop an innovative Covalent Organic Framework based on melamine-terephthalaldehyde (COF-MTF) for efficient and sustainable hydrogen storage.The COF-MTF was prepared by directly reacting melamine with terephthalaldehyde through a schiff base reaction.Characterization of the sample was conducted using various techniques, including thermogravimetric anal. (TGA), Fourier-transform IR spectroscopy (FTIR), SEM (SEM), and Brunauer-Emmett-Teller (BET) surface area anal.The synthesized COF-MTF networks demonstrated a significant BET surface area of 1986 m2.g-1.It demonstrated notable isosteric heat of adsorption values between 28.7 and 33.5 kJ/mol and achieved a maximum N2 uptake of 171 mg (N2)/g at 298 K and 25 atm.Subjected to repeated cycles of H2 gas adsorption, COF-MTF highlighted exceptional adsorbent stability, maintaining over 99.9 % of its adsorption capacity after 10 cycles.The calculated isosteric heat of hydrogen adsorption by the COF-MTF compound equals 8.447 KJ.mol-1.With relatively high H2 uptake, this study highlighted COF-MTF as a promising candidate for advancing green hydrogen storage technologies to achieve sustainable development goals (SDGs).